Diiodidobis(N,N,N′,N′-tetramethylthiourea-κS)cadmium(II)
نویسندگان
چکیده
In the title compound, [CdI(2)(C(5)H(12)N(2)S)(2)], the Cd(II) ion is located on a twofold rotation axis and is coordinated in a distorted tetra-hedral mode by two iodide ions and by two tetra-methyl-thio-urea (tmtu) ligands through their S atoms. The crystal structure is stabilized by C-H⋯N and C-H⋯S hydrogen bonds.
منابع مشابه
Dibromidobis(N,N,N′,N′-tetramethylthiourea-κS)cadmium(II)
In the title compound, [CdBr(2)(C(5)H(12)N(2)S)(2)], the Cd(II) atom lies on a twofold rotation axis. It exhibits a distorted tetra-hedral coordination environment defined by two S atoms of two tetra-methyl-thio-urea (tmtu) ligands and two bromide ions. The crystal structure is consolidated by C-H⋯N and C-H⋯S hydrogen bonds.
متن کاملDichloridobis(N,N,N′,N′-tetramethylthiourea-κS)mercury(II)
In the title compound, [HgCl(2)(C(5)H(12)N(2)S)(2)], the Hg(II) atom is located on a twofold rotation axis and is bonded in a distorted tetra-hedral coordination mode to two chloride ions and to two tetra-methyl-thio-urea (tmtu) mol-ecules through their S atoms. The crystal structure is stabilized by C-H⋯N and C-H⋯S hydrogen bonds.
متن کاملTetraaquabis(thiourea-κS)cadmium(II) triaquatris(thiourea-κS)cadmium(II) disulfate
The title compound, [Cd(CH(4)N(2)S)(2)(H(2)O)(4)][Cd(CH(4)N(2)S)(3)(H(2)O)(3)](SO(4))(2), contains two mol-ecules of each of the Cd complexes and four sulfate ions in the asymmetric unit: all the Cd atoms exhibit distorted octa-hedral geometries. The Cd-S and Cd-O bond lengths around the Cd atoms in the bis-(thio-urea) cations are in the ranges 2.580 (4)-2.599 (4) and 2.323 (8)-2.421 (9) Å, res...
متن کاملDicyanidobis(thiourea-κS)cadmium(II) monohydrate
In the title compound, [Cd(CN)(2)(CH(4)N(2)S)(2)]·H(2)O, the Cd atom lies on a twofold rotation axis and is bonded to two S atoms of thio-urea and two C atoms of the cyanide anions in a distorted tetra-hedral environment. The crystal structure is stabilized by N-H⋯N(CN), N-H⋯O, O-H⋯N and N-H⋯S hydrogen bonds.
متن کاملDiiodidobis(1-methylimidazole-κN 3)cadmium(II)
In the title compound, [CdI(2)(C(4)H(6)N(2))(2)], each Cd atom is coordinated by two N atoms from two 1-methylimidazole and two iodido ligands. The Cd atom has a distorted tetrahedral coordination. Inter-molecular C-H⋯I hydrogen bonds link the monomeric units, generating a one-dimensional supra-molecular chain along the a axis.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010